4,4′-Di-tert-butyl-2,2′-bipyridine

4,4′-Di-tert-butyl-2,2′-bipyridine

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In the title compound, C18H24N2, the molecular unit adopts a trans conformation around the central C—C swish supreme glide track white bond [N—C—C—N torsion angle of 179.2 (3)°], with the two aromatic rings almost coplanar [dihedral angle of only 0.70 (4)°].The crystal packing is driven by co-operative contacts involving weak C—H.

N and C—H.π interactions, and also the need Jeans to fill effectively the available space.